Synthesis and Structure of a New Din

Synthesis and Structure of a New Dinuclear Molybdenum (Ⅰ) Compound with Cyclohexanthiolate Ligand, [Mo2(SC6H11)2(CO)8]

Molybdenum(Ⅰ)-compound [Mo2(SC6H11)2(CO)8] 1, crystallizes in monoclinic, space group P21/c with a = 9.5863(9), b = 9.4469(9), c = 13.869(1) (A), β= 99.697(2)o, V = 1238.1(2)(A)3, Z = 2, Dc = 1.734 g/cm3, μ= 12.23 cm-1 and F(000) = 644. The final R = 0.0455 and wR = 0.1159 for 1590 observed reflections with I > 2((I). 1 possesses a rhombic bimetallic core MoS2Mo with the Mo-Mo bond length of 2.975(1) and Mo-S of 2.485(2) (A).

作 者： ZHOU Zhang-Feng ZHUANG Bo-Tao WEI Qiang PENG Sai-Qun WU Ke-Chen LIN Chen-Sheng   作者單位： State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China  刊 名： 結構化學  ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF STRUCTURAL CHEMISTRY  年，卷(期)： 2002 21(6)  分類號： O64  關鍵詞： molybdenum(Ⅰ)-compound   synthesis   structure  

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